多面體出版的原始，基礎，實驗和理論工作的最高質量在所有主要領域的無機化學。這包括合成化學、配位化學、有機金屬化學、生物無機化學以及固態和材料化學。論文應該是重要的工作，所有新的化合物必須有適當的特征。強烈建議將單晶X射線結構數據包括在內，但通常不考慮僅報告單一化合物的X射線結構測定的論文。關于固態或材料化學的論文預計將具有重要的分子化學成分（例如分子前體的合成和表征和/或對不同前體或反應條件的使用進行系統研究），或展示尖端應用（例如用于能源應用）。不考慮只涉及穩定常數的論文。多面體出版全篇論文，特別委托的評論文章（多面體評論）和期刊的主題期刊（多面體特刊）。多面體不出版通訊、筆記或書評。

Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry. Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.Polyhedron publishes full papers, specially commissioned review articles (Polyhedron Reviews) and themed issues of the journal (Polyhedron Special Issues). Polyhedron does not publish communications, notes or Book Reviews.